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Potterton 80e Hot Water Problem?

I have a Potterton 80e Boiler, my problem is that when I have the Heating and Hot water on together the Heating is Hot, but the Water only gets Warm at best.
If I switch the Heating off, and just have the Hot Water on, then the Water gets Piping Hot as it should do, Any Suggestions would be greatly appreciated.
Tony., June 2010
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