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How can I loosen a tight tap joint?

How can I loosen a very tight brass tap joint to change the washer? I have tried holding the tap spout while using a wrench on the hexagonal nut of the tap but it won't move. Help!
Douglas Stevens, April 2012
Spray WD40 leave 10 mits ,use socket with long handle to have better grip the one we use to undo car wheel nut

ltd, April 2012